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废旧聚氨酯材料的回收利用研究进展
Research Progress on Recycling of Waste Polyurethane Materials

DOI: 10.12677/aep.2024.142038, PP. 282-292

Keywords: 废旧聚氨酯,回收利用,化学回收,降解机理
Waste Polyurethane
, Recycling and Utilization, Chemical Recycling, Degradation Mechanism

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Abstract:

聚氨酯(PU)材料被广泛应用于家居、建筑、航天航空和医疗健康等领域,因此聚氨酯废弃物的数量不断增加。为了更好地理解废旧聚氨酯塑料的回收和降解机理,本文综述了目前常见的回收利用方法,并对这些方法的优缺点进行了讨论。值得一提的是,化学回收法能够高效地实现单体的回收和再利用,不仅减轻了环境压力,还带来了经济效益。
Polyurethane (PU) materials are widely used in fields such as home furnishings, construction, aerospace, and healthcare, which has led to an increasing amount of polyurethane waste. To gain a deeper understanding of the recycling and degradation mechanism of waste polyurethane plastics, this article reviews the commonly used recycling methods and discusses the advantages and disadvantages of various recycling methods. Among them, chemical recovery can efficiently achieve monomer recovery and reuse, truly realizing material recycling, reducing environmental pressure, and bringing economic benefits.

References

[1]  赵盐鹏, 葛志强, 姚南, 等. 废旧聚氨酯降解回收技术[J]. 化学推进剂与高分子材料, 2023, 21(3): 31-36.
[2]  赵亮, 张丽娟, 朱芸, 等. 聚氨酯的回收[J]. 中国胶粘剂, 2023, 32(2): 60-69.
[3]  秦颖, 王强强. 聚氨酯材料的发展现状[J]. 中国建材科技, 2017, 26(1): 39-41.
[4]  张良. 废聚氨酯硬泡醇解回收多元醇初步研究[D]: [硕士学位论文]. 重庆: 重庆大学, 2013.
[5]  胡朝辉, 王小妹, 许玉良. 醇解废旧聚氨酯回收多元醇研究进展[J]. 聚氨酯工业, 2008, 23(4): 9-11.
[6]  葛志强, 徐浩星, 李忠友, 程新丽. 聚氨酯废弃物的处理和回收利用[J]. 化学推进剂与高分子材料, 2008, 6(1): 65-68.
[7]  吴自强, 曹红军. 废聚氨酯的综合利用[J]. 再生资源研究, 2003(4): 19-23.
[8]  高劲成. 废旧聚氨酯泡沫降解新技术及其生命周期评价[D]: [硕士学位论文]. 长春: 长春工业大学, 2023.
[9]  Gogoi, D., Kumar, M. and Lakshmi, Y.G. (2023) A Comprehensive Review on “Pyrolysis” for Energy Recovery. BioEnergy Research, 16, 1417-1437.
https://doi.org/10.1007/s12155-023-10568-9
[10]  Hooper, J.F., Parrinello, G., Parfondry, A., et al. (1992) Recent Developments in the Chemical Recycling of Flexible Polyurethanes. Cellular Polymers, 11, 388-396.
https://doi.org/10.1177/026248939201100504
[11]  曹民干, 曹晓蓉. 聚氨酯硬质泡沫塑料的处理和回收利用[J]. 塑料, 2005, 34(1): 14-22.
[12]  彭磊. 精密铸造用陶瓷型壳微滴喷射粘结成型工艺及性能研究[D]: [硕士学位论文]. 武汉: 华中科技大学, 2022.
[13]  Schwartz, M.R., Capizzi, P.J., Movassaghi, K., et al. (2015) Sientra High-Strength Cohesive Shaped Technique: Roundtable Discussion. Aesthetic Surgery Journal, 35, S22-S32.
https://doi.org/10.1093/asj/sjv026
[14]  陈宏达, 曹东风, 胡海晓, 等. 连续纤维增强热塑性复合材料热压成型工艺研究进展[J]. 航空制造技术, 2023, 66(15): 24-37.
[15]  Himoto, I., Yamashita, S. and Kita, H. (2016) Heat Press Molding of Open-Celled Porous Si-SiC Ceramics Consisting of Skeletal Strut via Gelcasting with Flexible and Thermosetting Polyurethane Resin. Advanced Powder Technology, 27, 948-958.
https://doi.org/10.1016/j.apt.2016.02.031
[16]  Li, J., Zhu, H., Fang, D., Luo, Y., et al. (2023) Mechanochemistry Recycling of Polyurethane Foam Using Urethane Exchange Reaction. Journal of Environmental Chemical Engineering, 11, Article 110269.
https://doi.org/10.1016/j.jece.2023.110269
[17]  曹宇. 硬质聚氨酯材料降解绿色技术开发[D]: [硕士学位论文]. 长春: 长春工业大学, 2019.
[18]  Martins, L., Zanini, N., Pinheiro, L., et al. (2022) Valorization of Banana Peel Waste Used as Filler in Castor Oil Polyurethane Foam for Vegetal Oil Sorption. Journal of Natural Fibers, 19, 7806-7817.
https://doi.org/10.1080/15440478.2021.1958414
[19]  黄汉生. 废聚氨酯的回收[J]. 化工新型材料, 1998(7): 26-28.
[20]  Zahedifar, P., Pazdur, L., Vande Velde, C.M., et al. (2021) Multistage Chemical Recycling of Polyurethanes and Dicarbamates: A Glycolysis-Hydrolysis Demonstration. Sustainability, 13, Article 3583.
https://doi.org/10.3390/su13063583
[21]  王静荣, 陈大俊. 聚氨酯废弃物回收利用的物理化学方法[J]. 弹性体, 2003, 13(6): 61-65.
[22]  Gu, X., Wang, X., Guo, X., et al. (2023) Study and Characterization of Regenerated Hard Foam Prepared by Polyol Hydrolysis of Waste Polyurethane. Polymers, 15, Article 1445.
https://doi.org/10.3390/polym15061445
[23]  Branson, Y., S?ltl, S., Buchmann, C., et al. (2023) Urethanases for the Enzymatic Hydrolysis of Low Molecular Weight Carbamates and the Recycling of Polyurethanes. Angewandte Chemie International Edition, 62, e202216220.
https://doi.org/10.1002/anie.202216220
[24]  刘志阳, 官军, 吕维扬. 废弃聚酯的化学解聚技术及其高值化产品的研究进展[J]. 合成纤维工业, 2023, 46(1): 55-62.
[25]  杨雨涵, 王晓岩, 苑文仪, 等. 废旧冰箱聚氨酯资源化再利用技术研究进展[J]. 环境工程, 2018, 36(6): 134-139.
[26]  张刚, 徐金球. 废旧聚氨酯泡沫回收利用技术进展[J]. 塑料工业, 2014, 42(6): 12-49.
[27]  Kanaya, K. and Takahashi, S. (1994) Decomposition of Polyurethane Foams by Alkanolamines. Journal of Applied Polymer Science, 51, 675-682.
https://doi.org/10.1002/app.1994.070510412
[28]  He, H.W., Du, K.M., Yu, H.J., et al. (2023) A New Strategy for Efficient Chemical Degradation and Recycling of Polyurethane Materials: A Multi-Stage Degradation Method. Green Chemistry, 25, 6405-6415.
https://doi.org/10.1039/D3GC01244A
[29]  阮浩达. 废弃热固性聚氨酯回收再生制备及试验研究[D]: [硕士学位论文]. 合肥: 安徽建筑大学, 2023.
[30]  李金惠, 董庆银, 姚志通. 我国废旧电冰箱聚氨酯泡沫塑料管理现状及对策研究[J]. 中国环境科学, 2013, 33(12): 2262-2267.
[31]  Oenema, J., Liu, H., De Coensel, N., et al. (2022) Review on the Pyrolysis Products and Thermal Decomposition Mechanisms of Polyurethanes. Journal of Analytical and Applied Pyrolysis, 169, Article 105723.
https://doi.org/10.1016/j.jaap.2022.105723
[32]  Eschenbacher, A., Varghese, R.J., Weng, J., et al. (2021) Fast Pyrolysis of Polyurethanes and Polyisocyanurate with and without Flame Retardant: Compounds of Interest for Chemical Recycling. Journal of Analytical and Applied Pyrolysis, 160, Article 105374.
https://doi.org/10.1016/j.jaap.2021.105374
[33]  李策. 废旧聚氨酯的化学降解方法综述[J]. 知识经济, 2011(12): 91.
[34]  Munir, D., Irfan, M.F. and Usman, M.R. (2018) Hydrocracking of Virgin and Waste Plastics: A Detailed Review. Renewable and Sustainable Energy Reviews, 90, 490-515.
https://doi.org/10.1016/j.rser.2018.03.034
[35]  Zhou, W., Neumann, P., Al Batal, M., et al. (2021) Depolymerization of Technical-Grade Polyamide 66 and Polyurethane Materials through Hydrogenation. ChemSusChem, 14, 4176-4180.
https://doi.org/10.1002/cssc.202002465
[36]  鹿桂芳, 丁彦滨, 赵春山. 国内外化学法回收废旧聚氨酯研究进展[J]. 化学工程师, 2004, 18(10): 45-51.
[37]  吴自强, 黄永炳, 刘志宏. 废聚氨酯的循环利用[J]. 新型建筑材料, 2002(7): 25-27.
[38]  付凯, 张琳达, 阎振丽. 聚氨酯材料醇解法回收及高值化应用进展[J]. 现代化工, 2023, 43(10): 74-83.
[39]  刘晓慧. 基于废弃PET醇解二元醇的聚氨酯胶粘剂性能研究[D]: [硕士学位论文]. 西安: 西安理工大学, 2023.
[40]  王同. 废旧聚氨酯脲降解再生制备改性聚氨酯工艺研究[D]: [硕士学位论文]. 上海: 东华大学, 2023.
[41]  叶子玮, 张蕾蕾, 杨帆. 基于醇解法回收废弃聚氨酯的《化工原理》教学分析[J]. 云南化工, 2021, 48(11): 175-177.
[42]  Li, Q., Xu, W., Pang, Y., et al. (2019) Recovery of Polyols from Polyurethane Foam Wastes by Solvent Decomposition. IOP Conference Series: Earth and Environmental Science, 310, Article 042014.
https://doi.org/10.1088/1755-1315/310/4/042014
[43]  范影, 王莹莹, 王学勇. 聚氨酯废料化学回收综述[J]. 应用化工, 2019, 48(2): 451-457.
[44]  牟善友, 张国鹏, 魏慧. 废旧硬质聚氨酯泡沫塑料的回收处理技术现状[J]. 山东化工, 2017, 46(18): 198-199.
[45]  高玮婧. 废旧冰箱硬质聚氨酯材料的资源再利用[D]: [硕士学位论文]. 北京: 北京交通大学, 2013.
[46]  杨粉蓉. 软质聚氨酯废料的回收与再利用研究[D]: [硕士学位论文]. 西安: 西北大学, 2011.
[47]  Yang, Y. and Tang, D. (2023) Non-Isocyanate Polyurethanes by Alcoholysis of Alkyl Bisurea with Li Salt-Assisted Melting: Synthesis and Properties. Macromolecular Chemistry and Physics, 224, Article ID: 2200448.
https://doi.org/10.1002/macp.202200448
[48]  Amundarain, I., Miguel-Fernández, R., Asueta, A., et al. (2022) Synthesis of Rigid Polyurethane Foams Incorporating Polyols from Chemical Recycling of Post-Industrial Waste Polyurethane Foams. Polymers, 14, Article 1157.
https://doi.org/10.3390/polym14061157
[49]  Johansen, M.B., Donslund, B.S., Larsen, E., et al. (2023) Closed-Loop Recycling of Polyols from Thermoset Polyurethanes by Tert-Amyl Alcohol-Mediated Depolymerization of Flexible Foams. ACS Sustainable Chemistry & Engineering, 11, 10737-10745.
https://doi.org/10.1021/acssuschemeng.3c01469
[50]  Cevher, D. and Sürdem, S. (2021) Polyurethane Adhesive Based on Polyol Monomers BHET and BHETA Depolymerised from PET Waste. International Journal of Adhesion and Adhesives, 105, Article 102799.
https://doi.org/10.1016/j.ijadhadh.2020.102799
[51]  王新开. 聚氨酯降解及聚醚多元醇回收研究[D]: [硕士学位论文]. 湘潭: 湘潭大学, 2012.
[52]  陈海平, 乔迁, 涂根国. 聚氨酯材料的化学降解机理[J]. 辽宁化工, 2007, 36(8): 535-539.
[53]  方园, 赵新, 胡嘉琦. 废旧聚氨酯的回收利用[J]. 聚氨酯工业, 2009, 24(4): 9-12.
[54]  袁晓艳, 程原. 非异氰酸酯聚氨酯的研究进展[J]. 中国胶粘剂, 2014, 23(3): 49-52.
[55]  Chen, M., Ou, B., Guo, Y., et al. (2018) Preparation of an Environmentally Friendly Antifouling Degradable Polyurethane Coating Material Based on Medium-Length Fluorinated Diols. Journal of Macromolecular Science, Part A, 55, 483-488.
https://doi.org/10.1080/10601325.2018.1470466
[56]  Gu, X., Zhu, S., Liu, S., et al. (2023) Analysis of the Influencing Factors of the Efficient Degradation of Waste Polyurethane and Its Scheme Optimization. Polymers, 15, Article 2337.
https://doi.org/10.3390/polym15102337
[57]  冯绍华, 左建东, 刘忠杰. 废旧聚氨酯的醇解与利用[J]. 现代塑料加工应用, 2004, 16(1): 15-17.
[58]  Chang, T.C., Chiu, Y.S., Chen, H.B., et al. (1995) Degradation of Phosphorus-Containing Polyurethanes. Polymer Degradation and Stability, 47, 375-381.
https://doi.org/10.1016/0141-3910(94)00135-9
[59]  陈佳彬, 马猛, 朱佳杰. 废旧聚醚型聚氨酯软泡醇解回收及再利用[C]//浙江省复合材料学会, 2017创新驱动加快发展丽水生态工业——新材料学术论坛学术论文集: 2017年卷. 2017: 6.
[60]  Miguel-Fernández, R., Amundarain, I., Asueta, A., et al. (2022) Recovery of Green Polyols from Rigid Polyurethane Waste by Catalytic Depolymerization. Polymers, 14, Article 2936.
https://doi.org/10.3390/polym14142936
[61]  王静荣, 陈大俊. 聚氨酯废弃物的化学降解机理[J]. 高分子通报, 2004(2): 85-90.
[62]  Gama, N., Godinho, B., Marques, G., et al. (2021) Recycling of Polyurethane by Acidolysis: The Effect of Reaction Conditions on the Properties of the Recovered Polyol. Polymer, 219, Article 123561.
https://doi.org/10.1016/j.polymer.2021.123561
[63]  Broekema, F.I., Van Leeuwen, M.B.M., Van Minnen, B., et al. (2015) In vivo Degradation of Polyurethane Foam with 55 wt% Polyethylene Glycol. Journal of Biomedical Materials Research Part A, 103, 3666-3675.
https://doi.org/10.1002/jbm.a.35492
[64]  Kim, Y.D. and Kim, S.C. (1998) Effect of Chemical Structure on the Biodegradation of Polyurethanes under Composting Conditions. Polymer degradation and stability, 62, 343-352.
https://doi.org/10.1016/S0141-3910(98)00017-2
[65]  李晓静, 王磊, 潘振勇. 废旧聚氨酯泡沫的醇解以及醇解产物的应用[J]. 现代制造技术与装备, 2019(9): 176-177.
[66]  吴世杰. 废PET聚酯的乙二醇胺降解与再生水性聚氨酯的研究[D]: [硕士学位论文]. 长沙: 湖南大学, 2019.
[67]  Liu, J., Zeng, Q., Lei, H., et al. (2023) Biodegradation of Polyester Polyurethane by Cladosporium sp. P7: Evaluating Its Degradation Capacity and Metabolic Pathways. Journal of Hazardous Materials, 448, Article 130776.
https://doi.org/10.1016/j.jhazmat.2023.130776

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