This paper presents a study on CO2 atmospheric transformation which was reacted directly with lithium hydroxide solution and metallic lithium. This solution was obtained through the reaction between metallic lithium and deionized water where hydrogen is produced and by exposing the metal at ambient conditions. In the transformation process, atmospheric CO2 gas reacts directly with LiOH solution, in both cases, the CO2 transformation kinetics was different. For this purpose, reactions between CO2 and LiOH solution were carried out under controlled temperature and the second process only with metallic lithium, which was exposed at room temperature, however, in these two processes lithium carbonate oxide was formed and identified. According to the results, the efficiency in CO2 transformation is a function of temperature value which was variable until completely obtaining the by-product, its XRD characterization indicated the formation only of Li2CO3 in both procedures. Under laboratory conditions lithium compounds selectively reacted with CO2. In the same way, there is an alternative procedure to obtain LiOH and Li2CO3 for different applications in various areas.
References
[1]
Kim, S., Choi, M., Kang, J.S., Joo, H., Park, B.H., Sung, Y.E. and Yoon, J. (2021) Electrochemical Recovery of LiOH from Used CO2 Adsorbents. CatalysisToday, 359, 83-89. https://doi.org/10.1016/j.cattod.2019.06.056
[2]
Zilberman, P. (2015) The CO2 Absorber Based on LiOH. ActaMedicaMarisiensis, 61, 4-6. https://doi.org/10.1515/amma-2015-0023
[3]
Kaneco, S., Katsumata, H., Suzuki, T. and Ohta, K. (2006) Photoelectrocatalytic Reduction of CO2 in LiOH/Methanol at Metal-Modified p-InP Electrodes. AppliedCatalysisB: Environmental, 64, 139-145. https://doi.org/10.1016/j.apcatb.2005.11.012
[4]
Yang, X., Li, S., Zhao, J., Huang, H. and Deng, L. (2022) Development of Covalent-Organic Frameworks Derived Hierarchical Porous Hollow Carbon Spheres Based LiOH Composites for Thermochemical Heat Storage. EnergyChemistry, 73, 301-310. https://doi.org/10.1016/j.jechem.2022.06.022
[5]
Cho, Y., Lee, J.Y., Bokare, A.D., Kwon, S.B., Park, D.S., Jung, W.S. and Choi, W. (2015) LiOH-Embedded Zeolite for Carbon Dioxide Capture under Ambient Conditions. JournalofIndustrialandEngineeringChemistry, 22, 350-356. https://doi.org/10.1016/j.jiec.2014.07.030
[6]
Izquierdo, M.T., Gasquet, V., Sansom, E., Ojeda, M., Garcia, S. and Maroto-Valer, M.M. (2018) Lithium-Based Sorbents for High Temperature CO2 Capture: Effect of Precursor Materials and Synthesis Method. Fuel, 230, 45-51. https://doi.org/10.1016/j.fuel.2018.05.041
[7]
Chang, Y., Huang, H., Wang, L., Li, Y. and Zhong, C. (2020) Synergistic Dual-Li Sites for CO2 Separation in Metal-Organic Framework Composites. ChemicalEngineeringJournal, 402, Article ID: 126201. https://doi.org/10.1016/j.cej.2020.126201
[8]
Grasso, M.L., Arneodo, L.P. and Gennari, F.C. (2020) CO2 Capture Properties of Li4SiO4 after Aging in Air at Room Temperature. JournalofCO2Utilization, 38, 232-240. https://doi.org/10.1016/j.jcou.2020.02.002
[9]
Yang, Y., Yao, S., Hu, Y., Sun, J., Cao, J., Li, Q. and Liu W. (2020) Mechanochemically Activated Li4SiO4-Based Adsorbent with Enhanced CO2 Capture Performance and Its Modification Mechanisms. Fuel, 273, Article ID: 117749. https://doi.org/10.1016/j.fuel.2020.117749
[10]
Zhao, Y., Xiang, X., Wang, M., Wang, H., Li, Y., Li, J. and Yang, H. (2021) Preparation of LiOH through BMED Process from Lithium-Containing Solutions: Effects of Coexisting Ions and Competition between Na and Li. Desalination, 512, Article ID: 115126. https://doi.org/10.1016/j.desal.2021.115126
[11]
Joo, S., Shim, H.W., Choi, J.J., Lee, C.G. and Kim, D.G. (2020) A Method of Synthesizing Lithium Hydroxide Nanoparticles Using Lithium Sulfate from Spent Batteries by 2-Step Precipitation Method. KoreanJournalofMetalsandMaterials, 58, 286-291. https://doi.org/10.3365/KJMM.2020.58.4.286
[12]
Lin, J., Li, Q., Chen, X., Li, C., Lu, S. and Liew, K.M. (2019) Sorption-Enhanced CO Capture over Cu-Mn-Ce Composite Oxides with LiOH Addition: CO Oxidation and in-Situ CO2 Sorption. ChemicalEngineeringJournal, 371, 267-275. https://doi.org/10.1016/j.cej.2019.04.049
[13]
Zhao, Y., Wang, H., Li, Y., Wang, M. and Xiang, X. (2020) An Integrated Membrane Process for Preparation of Lithium Hydroxide from High Mg/Li Ratio Salt Lake Brine. Desalination, 493, Article ID: 114620. https://doi.org/10.1016/j.desal.2020.114620
Liu, H. and Azimi, G. (2022) Production of Battery Grade Lithium Hydroxide Monohydrate Using Barium Hydroxide Causticizing Agent. Resources, ConservationandRecycling, 179, Article ID: 106115. https://doi.org/10.1016/j.resconrec.2021.106115
[16]
Stefanelli, E., Puccini, M., Vitolo, S. and Seggiani, M. (2020) CO2 Sorption Kinetic Study and Modeling on Doped-Li4SiO4 under Different Temperatures and CO2 Partial Pressures. ChemicalEngineeringJournal, 379, Article ID: 122307. https://doi.org/10.1016/j.cej.2019.122307
[17]
Miao, Y., Pudukudy, M., Zhi, Y., Miao, Y., Shan, S., Jia, Q. and Ni, Y. (2020) A Facile Method for in Situ Fabrication of Silica/Cellulose Aerogels and Their Application in CO2 Capture. CarbohydratePolymers, 236, Article ID: 116079. https://doi.org/10.1016/j.carbpol.2020.116079
[18]
Wang, J., Park, Y.K. and Jo, Y.M. (2020) Sequential Improvement of Activated Carbon Fiber Properties for Enhanced Removal Efficiency of Indoor CO2. JournalofIndustrialandEngineeringChemistry, 89, 400-408. https://doi.org/10.1016/j.jiec.2020.06.011
[19]
Chen, X., Zhao, Z., Hao, M. and Wang, D. (2013) Research of Hydrogen Generation by the Reaction of Al-Based Materials with Water. JournalofPowerSources, 222, 188-195. https://doi.org/10.1016/j.jpowsour.2012.08.078
[20]
Khzouz, M., Gkanas, E.I., Girella, A., Statheros, T. and Milanese, C. (2020) Sustainable Hydrogen Production via LiH Hydrolysis for Unmanned Air Vehicle (UAV) Applications. InternationalJournalofHydrogenEnergy, 45, 5384-5394. https://doi.org/10.1016/j.ijhydene.2019.05.189
[21]
Li, J.R., Ma, Y., McCarthy, M.C., Sculley, J., Yu, J., Jeong, H.K., Balbuena, P.B. and Zhou, H. (2011) Carbon Dioxide Capture-Related Gas Adsorption and Separation in Metal-Organic Frameworks. CoordinationChemistryReviews, 255, 1791-1823. https://doi.org/10.1016/j.ccr.2011.02.012
[22]
Liu, Y., Wang, Z.U. and Zhou, H.C. (2012) Recent Advances in Carbon Dioxide Capture with Metal-Organic Frameworks. Greenhouse Gases: Science and Technology, 2, 239-259. https://doi.org/10.1002/ghg.1296
[23]
Park, Y., Moon, D.K., Kim, Y.N., Ahn, H. and Lee, C.H. (2014) Adsorption Isotherms of CO2, CO, N2, CH4, Ar and H2 on Activated Carbon and Zeolite LiX up to 1.0 MPa. Adsorption, 20, 631-647. https://doi.org/10.1007/s10450-014-9608-x
[24]
Rashidi, N.A. and Yusup, S. (2016) An Overview of Activated Carbons Utilization for the Post-Combustion Carbon Dioxide Capture. JournalofCO2Utilization, 13, 1-16. https://doi.org/10.1016/j.jcou.2015.11.002
[25]
Iturbe-García, J.L., Bonifacio, J., Granados, F. and López-Muñoz, B.E. (2019) Behavior of a Hydrotalcite Type Material Obtained from MgAl Alloy for CO2 Adsorption. AppliedClayScience, 183, Article ID: 105296. https://doi.org/10.1016/j.clay.2019.105296