Metallic materials are used in many applications due to their mechanical and physical properties. Under an aggressive environment, i.e. high temperature and/or corrosive environment these materials can be degraded at a fast rate. One way to protect the metal surface against corrosion is to apply the organic inhibitor material. The inhibitor will normally be chemically adsorbed by the surface of the metal; this will form a protective thin film. The current work is to investigate the influences of the Tarmarix plant as an organic material source for inhibiting carbon steel in corrosion media. The obtained results show that the changes in weight loss because of the corrosion in samples immersed in corrosion media containing 10% and 20% of Tarmaix; were less than in samples immersed in the same media without the Tarmaix. The corrosion rate decreased with time for all inhabitation specimens. The results revealed that longer time exposure to the inhibitor material results in higher inhibition efficiency which was above 90% efficiency. And the plots of C\θ versus C give straight lines with the linear correlation coefficient (R2) values close to unity, which follow the Langmuir adsorption isotherm. The slope ranges of these lines are 1.391 - 1.623 within the used immersion times. Therefore, it can be suggested that the absorbed molecules form a monolayer on the mild steel surface. The strong appearance of functional groups such as C-OH inside the structure of polyphenolics in the plant leaf extract of Tarmaix could probably be responsible for the reduction of metal ions and the formation of a protective layer that improved the corrosion process within the inhabitation samples.
References
[1]
Eliaz, N. (2019) Corrosion of Metallic Biomaterials: A Review. Materials, 12, Article No. 407. https://doi.org/10.3390/ma12030407
[2]
Rani, B.E.A. and Basu, B.B.J. (2012) Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview. International Journal of Corrosion, 2012, Article ID: 380217. https://doi.org/10.1155/2012/380217
[3]
Castro-Díez, P., Vaz, A.S., Silva, J.S., van Loo, M., Alonso, á., Aponte, C., et al. (2019) Global Effects of Non-Native Tree Species on Multiple Ecosystem Services. Biological Reviews, 94, 1477-1501. https://doi.org/10.1111/brv.12511
[4]
Yin, C., Kong, M., Zhang, J., Wang, Y., Ma, Q., Chen, Q., et al. (2020) Influence of Hydroxyl Groups on the Inhibitive Corrosion of Gemini Surfactant for Carbon Steel. ACS Omega, 5, 2620-2629. https://doi.org/10.1021/acsomega.9b02989
[5]
Marzorati, S., Verotta, L. and Trasatti, S.P. (2018) Green Corrosion In-hibitors from Natural Sources and Biomass Wastes. Molecules, 24, Article No. 48. https://doi.org/10.3390/molecules24010048
[6]
Fernine, Y., Salim, R., Arrousse, N., Haldhar, R., El Hajjaji, F., Kim, S., et al. (2022) Anti-Corrosion Performance of Ocimum basilicum Seed Extract as Environmental Friendly Inhibitors for Mild Steel in HCl Solution: Evaluations of Electrochemical, EDX, DFT and Monte Carlo. Journal of Molecular Liquids, 355, Article ID: 118867. https://doi.org/10.1016/j.molliq.2022.118867
[7]
Kadhim, A., Betti, N., Al-Bahrani, H.A., Al-Ghezi, M.K.S., Gaaz, T., Kadhum, A.H. and Alamiery, A. (2021) A Mini Review on Corrosion, Inhibitors and Mechanism Types of Mild Steel Inhibition in an Acidic Environment. International Journal of Corrosion and Scale Inhibition, 10, 861-884.
[8]
Ahmed, M.H.O., Al-Amiery, A.A., Al-Majedy, Y.K., Kadhum, A.A.H., Mohamad, A.B. and Gaaz, T.S. (2018) Synthesis and Characteri-zation of a Novel Organic Corrosion Inhibitor for Mild Steel in 1 M Hydrochloric Acid. Results in Physics, 8, 728-733. https://doi.org/10.1016/j.rinp.2017.12.039
[9]
Ahmed, M.H.O., Al-Amiery, A.A., Al-Majedy, Y.K., Kadhum, A.A.H., Mo-hamad, A.B. and Gaaz, T.S. (2018) Synthesis and Characterization of a Novel Organic Corrosion Inhibitor for Mild Steel in 1 M Hydrochloric Acid. Results in Physics, 8, 728-733. https://doi.org/10.1016/j.rinp.2017.12.039
[10]
Ojong, O.E., Zina, J., Omeke, W.C., Ekpenyong, A.A., Wilson, D., Uloma, A.C., et al. (2023) The Use of Models to Evaluate Corrosion Effects on Mild Steel Heat Exchanger in Water and Mono Ethanol Amine (MEA). Advances in Chemical Engineering and Science, 13, 336-350. https://doi.org/10.4236/aces.2023.134023
[11]
Abbas, A., Adesina, A.Y. and Suleiman, R.K. (2023) Influence of Organic Acids and Related Organic Compounds on Corrosion Behavior of Stainless Steel—A Critical Review. Metals, 13, Article No. 1479. https://doi.org/10.3390/met13081479
[12]
Singh, J.K., Mandal, S., Lee, H. and Yang, H. (2021) Effect of Chloride Ions Concentrations to Breakdown the Passive Film on Rebar Surface Exposed to L-Arginine Containing Pore Solution. Materials, 14, Article No. 5693. https://doi.org/10.3390/ma14195693
[13]
Eziuka, J.E., Onyeachu, I.B., Njoku, D.I., Nwanonenyi, S.C., Chidiebere, M.A. and Oguzie, E.E. (2023) Elucidating the Inhibition Behavior of Pterocarpus santa-linoides Leaves Extract on Mild Steel Corrosion in H2SO4 Solution-GC-MS, FTIR, SEM, Experimental and Computational Ap-proach. Moroccan Journal of Chemistry, 14, 579-593.
[14]
Bösing, I., Thöming, J. and Baune, M. (2017) Electrolyte Com-position for Distinguishing Corrosion Mechanisms in Steel Alloy Screening. International Journal of Corrosion, 2017, Article ID: 9425864. https://doi.org/10.1155/2017/9425864
[15]
Christopher, N.M., Deborah, C.O., Bonaventure, C.U., Michael, G.A., Chukwunonso, S.N., Obinna, L.I., et al. (2023) Evaluation of Corrosion Characteristics of Mild Steel in the Acidic Envi-ronment Using Cocoyam and Almond Leaves Extracts as Inhibitors. Journal of Civil Engineering and Environmental Scienc-es, 9, 20-24. https://doi.org/10.17352/2455-488x.000063
[16]
Kaya, F., Solmaz, R. and Halil Geçibesler, İ. (2023) The Use of Methanol Extract of Rheum Ribes (Işgın) Flower as a Natural and Promising Corrosion Inhibitor for Mild Steel Protec-tion in 1 m HCl Solution. Journal of Industrial and Engineering Chemistry, 122, 102-117. https://doi.org/10.1016/j.jiec.2023.02.013
[17]
Ali, I.H. (2021) Experimental, DFT and MD Assessments of Bark Extract of Tamarix aphylla as Corrosion Inhibitor for Carbon Steel Used in Desalination Plants. Molecules, 26, Article No. 3679. https://doi.org/10.3390/molecules26123679
[18]
Kherraf, S., Ammouchi, N. and Zouaoui, E. (2019) Corrosion Inhibition Properties of Cinnamon Extract on Monel 400 in Hydrochloric Acid Solution. International Review of Mechanical Engineer-ing (IREME), 13, 350. https://doi.org/10.15866/ireme.v13i6.17090
[19]
Akinbulumo, O.A., Odejobi, O.J. and Odekanle, E.L. (2020) Thermodynamics and Adsorption Study of the Corrosion Inhibition of Mild Steel by Euphorbia heterophylla L. Extract in 1.5 m HCl. Results in Materials, 5, Article ID: 100074. https://doi.org/10.1016/j.rinma.2020.100074
[20]
Mahmou, C., Bouissoui, E.M., Bouhlal, F., Labjar, N., Merimi, I., Kaya, S., El Ibrahimi, B., Chellouli, M., Dahrouch, A. and El Hajjaji, S. (2021) Synergistic Effects of Aminotris (Methylene Phos-phonic Acid) and Zn2 on the Carbon Steel Corrosion in Acid Media: An Experimental and Theoretical Approach. The In-ternational Journal of Corrosion and Scale Inhibition, 10, 1245-1281.
[21]
Chakravarthy, M.P. and Mohana, K.N. (2014) Adsorption and Corrosion Inhibition Characteristics of Some Nicotinamide Derivatives on Mild Steel in Hydrochloric Acid Solution. ISRN Corrosion, 2014, Article ID: 687276. https://doi.org/10.1155/2014/687276
[22]
Vaszilcsin, C.G., Putz, M.V., Kellenberger, A. and Dan, M.L. (2023) On the Evaluation of Metal-Corrosion Inhibitor Interactions by Adsorption Iso-therms. Journal of Molecular Structure, 1286, Article ID: 135643. https://doi.org/10.1016/j.molstruc.2023.135643
[23]
Shi, L., Zhao, W., Yang, Z., Subbiah, V. and Suleria, H.A.R. (2022) Extraction and Characterization of Phenolic Compounds and Their Potential Antioxidant Activities. Environmental Science and Pollution Research, 29, 81112-81129. https://doi.org/10.1007/s11356-022-23337-6