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Green Chemistry Based Benign Routes for Nanoparticle Synthesis

DOI: 10.1155/2014/302429

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Abstract:

Green chemistry has been an eye catching area of interest since the past few years. With the problem of energy crisis looming high and its constraint being particularly vulnerable on the developing economies, the need for giving alternative traditional chemistry a serious consideration as well as adequate room for development has received significant boost through the coveted efforts of multidisciplinary and interdisciplinary scientific fields. Nanoscience has been the right field in this dimension as it opens up the door to multiple opportunities through enabling a number of chemical, biochemical, and biophysical transformations in a significantly easier and reliable manner. The use of nanoparticles has made the fields of catalysis, synthesis, and enzyme immobilizations as well as molecular interactions a lot much easier, rapid and easily controllable. This review article sheds light on the popular alternative synthesis routes being employed for the synthesis of nanoparticles, the pivotal being from microbes, plants, and chemical routes via sonication, microwaving, and many others. 1. Introduction Ever since the realization of unconventional properties of matter at nanoscale has assumed significant proportions, there have been numerous attempts to synthesize metallic and metal oxide based nanoparticles through several nonconventional routes. Nanotechnology has just occupied a very special place in the minds of researchers of chemical, biological, and physical backgrounds, which is especially interesting with the quantitative as well as qualitative outputs of nanoparticles. Though not all but silver, gold, zinc oxide, and platinum based nanoparticles have occupied the centre stage till now. The reason being obvious is that they are inert in themselves and can facilitate the surrounding chemical reactions increasingly well. Interestingly, the properties of nanoparticles synthesized using different routes have been found to be sufficiently different, which makes these routes even more powerful. Very easy and economical routes for their synthesis have been discovered. These do not require the technical expertise of well-equipped laboratory professionals. Moreover, these are relatively quicker in terms of output and can be carried out even at grass route levels, ranging from the vegetables we eat, plants we grow, and microbes we admire for their genetic diversities. The reason for the increasing interest in the synthesis of metal and metal oxide based nanoparticles through these routes lies behind their extraordinary abilities to function as catalysts and

References

[1]  N. Jain, A. Bhargava, S. Majumdar, J. C. Tarafdar, and J. Panwar, “Extracellular biosynthesis and characterization of silver nanoparticles using Aspergillus flavus NJP08: a mechanism perspective,” Nanoscale, vol. 3, no. 2, pp. 635–641, 2011.
[2]  K. S. Suslick, Ed., Ultrasound: Its Chemical, Physical and Biological Effects, Wiley-VCH, Weinheim, Germany, 1988.
[3]  T. Klaus, R. Joerger, E. Olsson, and C. Granqvist, “Silver-based crystalline nanoparticles, microbially fabricated,” Proceedings of the National Academy of Sciences of the United States of America, vol. 96, no. 24, pp. 13611–13614, 1999.
[4]  A. K. Jha, K. Prasad, and A. R. Kulkarni, “Synthesis of TiO2 nanoparticles using microorganisms,” Colloids and Surfaces B, vol. 71, no. 2, pp. 226–229, 2009.
[5]  A. Bharde, A. Wani, Y. Shouche, P. A. Joy, B. L. V. Prasad, and M. Sastry, “Bacterial aerobic synthesis of nanocrystalline magnetite,” Journal of the American Chemical Society, vol. 127, no. 26, pp. 9326–9327, 2005.
[6]  M. I. Husseiny, M. A. El-Aziz, Y. Badr, and M. A. Mahmoud, “Biosynthesis of gold nanoparticles using Pseudomonas aeruginosa,” Spectrochimica Acta A, vol. 67, no. 3-4, pp. 1003–1006, 2007.
[7]  R. Y. Sweeney, C. Mao, X. Gao et al., “Bacterial biosynthesis of cadmium sulfide nanocrystals,” Chemistry and Biology, vol. 11, no. 11, pp. 1553–1559, 2004.
[8]  S. He, Z. Guo, Y. Zhang, S. Zhang, J. Wang, and N. Gu, “Biosynthesis of gold nanoparticles using the bacteria Rhodopseudomonas capsulata,” Materials Letters, vol. 61, no. 18, pp. 3984–3987, 2007.
[9]  P. Mukherjee, A. Ahmad, D. Mandal et al., “Bioreduction of AuCl4? ions by the fungus, Verticillium sp. and surface trapping of the gold nanoparticles formed,” Angewandte Chemie International Edition, vol. 40, no. 19, pp. 3585–3588, 2001.
[10]  N. Vigneshwaran, N. M. Ashtaputre, P. V. Varadarajan, R. P. Nachane, K. M. Paralikar, and R. H. Balasubramanya, “Biological synthesis of silver nanoparticles using the fungus Aspergillus flavus,” Materials Letters, vol. 61, no. 6, pp. 1413–1418, 2007.
[11]  A. Ahmad, S. Senapati, M. I. Khan, R. Kumar, and M. Sastry, “Extra-/intracellular biosynthesis of gold nanoparticles by an alkalotolerant fungus, Trichothecium sp.,” Journal of Biomedical Nanotechnology, vol. 1, no. 1, pp. 47–53, 2005.
[12]  P. Mukherjee, A. Ahmad, D. Mandal et al., “Fungus-mediated synthesis of silver nanoparticles and their immobilization in the mycelial matrix: a novel biological approach to nanoparticle synthesis,” Nano Letters, vol. 1, no. 10, pp. 515–519, 2001.
[13]  P. Mukherjee, S. Senapati, D. Mandal et al., “Extracellular synthesis of gold nanoparticles by the fungus Fusarium oxysporum,” ChemBioChem, vol. 3, no. 5, pp. 461–463, 2002.
[14]  S. S. Shankar, A. Ahmad, R. Pasricha, and M. Sastry, “Bioreduction of chloroaurate ions by geranium leaves and its endophytic fungus yields gold nanoparticles of different shapes,” Journal of Materials Chemistry, vol. 13, no. 7, pp. 1822–1826, 2003.
[15]  A. K. Gade, P. Bonde, A. P. Ingle, P. D. Marcato, N. Durán, and M. K. Rai, “Exploitation of Aspergillus niger for synthesis of silver nanoparticles,” Journal of Biobased Materials and Bioenergy, vol. 2, no. 3, pp. 243–247, 2008.
[16]  D. Philip, “Biosynthesis of Au, Ag and Au–Ag nanoparticles using edible mushroom extract,” Spectrochimica Acta A, vol. 73, no. 2, pp. 374–381, 2009.
[17]  K. Kathiresan, S. Manivannan, M. A. Nabeel, and B. Dhivya, “Studies on silver nanoparticles synthesized by a marine fungus, Penicillium fellutanum isolated from coastal mangrove sediment,” Colloids and Surfaces B, vol. 71, no. 1, pp. 133–137, 2009.
[18]  S. A. Kumar, A. A. Ansary, A. Abroad, and M. I. Khan, “Extracellular biosynthesis of CdSe quantum dots by the fungus, Fusarium oxysporum,” Journal of Biomedical Nanotechnology, vol. 3, no. 2, pp. 190–194, 2007.
[19]  A. Bharde, D. Rautaray, V. Bansal, et al., “Extracellular biosynthesis of magnetite using fungi,” Small, vol. 2, no. 1, pp. 135–141, 2006.
[20]  V. Bansal, D. Rautaray, A. Ahmad, and M. Sastry, “Biosynthesis of zirconia nanoparticles using the fungus Fusarium oxysporum,” Journal of Materials Chemistry, vol. 14, no. 22, pp. 3303–3305, 2004.
[21]  V. Bansal, D. Rautaray, A. Bharde et al., “Fungus-mediated biosynthesis of silica and titania particles,” Journal of Materials Chemistry, vol. 15, no. 26, pp. 2583–2589, 2005.
[22]  W. Shenton, T. Douglas, M. Young, G. Stubbs, and S. Mann, “Inorganic-organic nanotube composites from template mineralization of tobacco mosaic virus,” Advanced Materials, vol. 11, no. 3, pp. 253–256, 1999.
[23]  S. W. Lee, C. Mao, C. E. Flynn, and A. M. Belcher, “Ordering of quantum dots, using genetically engineered viruses,” Science, vol. 296, no. 5569, pp. 892–895, 2002.
[24]  C. Mao, C. E. Flynn, A. Hayhurst et al., “Viral assembly of oriented quantum dot nanowires,” Proceedings of the National Academy of Sciences of the United States of America, vol. 100, no. 12, pp. 6946–6951, 2003.
[25]  C. T. Dameron, R. N. Reese, R. K. Mehra et al., “Biosynthesis of cadmium sulphide quantum semiconductor crystallites,” Nature, vol. 338, no. 6216, pp. 596–597, 1989.
[26]  M. Kowshik, W. Vogel, J. Urban, S. K. Kulkarni, and K. M. Paknikar, “Microbial synthesis of semiconductor PbS nanocrystallites,” Advanced Materials, vol. 14, no. 11, pp. 815–818, 2002.
[27]  M. Kowshik, N. Deshmukh, W. Vogel, J. Urban, S. K. Kulkarni, and K. M. Paknikar, “Microbial synthesis of semiconductor CdS nanoparticles, their characterization, and their use in the fabrication of an ideal diode,” Biotechnology and Bioengineering, vol. 78, no. 5, pp. 583–588, 2002.
[28]  M. Kowshik, S. Ashtaputre, S. Kharrazi et al., “Extracellular synthesis of silver nanoparticles by a silver-tolerant yeast strain MKY3,” Nanotechnology, vol. 14, no. 1, pp. 95–100, 2003.
[29]  J. L. Gardea-Torresdey, E. Gomez, J. R. Peralta-Videa, J. G. Parsons, H. Troiani, and M. Jose-Yacaman, “Alfalfa sprouts: a natural source for the synthesis of silver nanoparticles,” Langmuir, vol. 19, no. 4, pp. 1357–1361, 2003.
[30]  S. S. Shankar, A. Rai, A. Ahmad, and M. Sastry, “Rapid synthesis of Au, Ag, and bimetallic Au core-Ag shell nanoparticles using Neem (Azadirachta indica) leaf broth,” Journal of Colloid and Interface Science, vol. 275, no. 2, pp. 496–502, 2004.
[31]  P. Daisy and K. Saipriya, “Biochemical analysis of Cassia fistula aqueous extract and phytochemically synthesized gold nanoparticles as hypoglycemic treatment for diabetes mellitus,” International Journal of Nanomedicine, vol. 7, pp. 1189–1202, 2012.
[32]  X. Yang, Q. Li, H. Wang et al., “Green synthesis of palladium nanoparticles using broth of Cinnamomum camphora leaf,” Journal of Nanoparticle Research, vol. 12, no. 5, pp. 1589–1598, 2010.
[33]  S. Joglekar, K. Kodam, M. Dhaygude, and M. Hudlikar, “Novel route for rapid biosynthesis of lead nanoparticles using aqueous extract of Jatropha curcas L. latex,” Materials Letters, vol. 65, no. 19-20, pp. 3170–3172, 2011.
[34]  H. J. Lee, G. Lee, N. R. Jang, et al., “Biological synthesis of copper nanoparticles using plant extract,” Nanotechnology, vol. 1, pp. 371–374, 2011.
[35]  T. Santhoshkumar, A. A. Rahuman, G. Rajakumar et al., “Synthesis of silver nanoparticles using Nelumbo nucifera leaf extract and its larvicidal activity against malaria and filariasis vectors,” Parasitology Research, vol. 108, no. 3, pp. 693–702, 2011.
[36]  A. K. Mittal, A. Kaler, and U. C. Banerjee, “Free radical scavenging and antioxidant activity of silver nanoparticles synthesized from flower extract of Rhododendron dauricum,” Nano Biomedicine and Engineering, vol. 4, no. 3, pp. 118–124, 2012.
[37]  A. K. Mittal, Y. Chisti, and U. C. Banerjee, “Synthesis of metallic nanoparticles using plant extracts,” Biotechnology Advances, vol. 31, no. 2, pp. 346–356, 2013.
[38]  Q. L. Feng, J. Wu, G. Q. Chen, F. Z. Cui, T. N. Kim, and J. O. Kim, “A mechanistic study of the antibacterial effect of silver ions on Escherichia coli and Staphylococcus aureus,” Journal of Biomedical Materials Research, vol. 52, no. 4, pp. 662–668, 2000.
[39]  J. R. Morones, J. L. Elechiguerra, A. Camacho et al., “The bactericidal effect of silver nanoparticles,” Nanotechnology, vol. 16, no. 10, pp. 2346–2353, 2005.
[40]  S. Shivaji, S. Madhu, and S. Singh, “Extracellular synthesis of antibacterial silver nanoparticles using psychrophilic bacteria,” Process Biochemistry, vol. 46, no. 9, pp. 1800–1807, 2011.
[41]  M. F. Lengke, M. E. Fleet, and G. Southam, “Biosynthesis of silver nanoparticles by filamentous cyanobacteria from a silver(I) nitrate complex,” Langmuir, vol. 23, no. 5, pp. 2694–2699, 2007.
[42]  N. Durán, P. D. Marcato, O. L. Alves, G. I. H. de Souza, and E. Esposito, “Mechanistic aspects of biosynthesis of silver nanoparticles by several Fusarium oxysporum strains,” Journal of Nanobiotechnology, vol. 3, article 8, 2005.
[43]  N. Vigneshwaran, N. M. Ashtaputre, P. V. Varadarajan, R. P. Nachane, K. M. Paralikar, and R. H. Balasubramanya, “Biological synthesis of silver nanoparticles using the fungus Aspergillus flavus,” Materials Letters, vol. 61, no. 6, pp. 1413–1418, 2007.
[44]  R. Y. Parikh, S. Singh, B. L. V. Prasad, M. S. Patole, M. Sastry, and Y. S. Schouche, “Extracellular synthesis of crystalline silver nanoparticles and molecular evidence of silver resistance from Morganella sp.: towards understanding biochemical synthesis mechanism,” ChemBioChem, vol. 9, no. 9, pp. 1415–1422, 2008.
[45]  S. Mann, “Bacteria and the midas touch,” Nature, vol. 357, no. 6377, pp. 358–360, 1992.
[46]  T. J. Beveridge and R. G. E. Murray, “Sites of metal deposition in the cell wall of Bacillus subtilis,” Journal of Bacteriology, vol. 141, no. 2, pp. 876–887, 1980.
[47]  L. Du, H. Jiang, X. Liu, and E. Wang, “Biosynthesis of gold nanoparticles assisted by Escherichia coli DH5α and its application on direct electrochemistry of hemoglobin,” Electrochemistry Communications, vol. 9, no. 5, pp. 1165–1170, 2007.
[48]  Y. Park, Y. N. Hong, A. Weyers, Y. S. Kim, and R. J. Linhardt, “Polysaccharides and phytochemicals: a natural reservoir for the green synthesis of gold and silver nanoparticles,” IET Nanobiotechnology, vol. 5, no. 3, pp. 69–78, 2011.
[49]  D. MubarakAli, N. Thajuddin, K. Jeganathan, and M. Gunasekaran, “Plant extract mediated synthesis of silver and gold nanoparticles and its antibacterial activity against clinically isolated pathogens,” Colloids and Surfaces B, vol. 85, no. 2, pp. 360–365, 2011.
[50]  B. Ankamwar, “Biosynthesis of gold nanoparticles (green-gold) using leaf extract of Terminalia catappa,” E-Journal of Chemistry, vol. 7, no. 4, pp. 1334–1339, 2010.
[51]  S. A. Babu and H. G. Prabu, “Synthesis of AgNPs using the extract of Calotropis procera flower at room temperature,” Materials Letters, vol. 65, no. 11, pp. 1675–1677, 2011.
[52]  J. Banerjee and R. T. Narendhirakannan, “Biosynthesis of silver nanoparticles from Syzygium cumini (L.) seed extract and evaluation of their in vitro antioxidant activities,” Digest Journal of Nanomaterials and Biostructures, vol. 6, no. 3, pp. 961–968, 2011.
[53]  A. Bankar, B. Joshi, A. R. Kumar, and S. Zinjarde, “Banana peel extract mediated novel route for the synthesis of silver nanoparticles,” Colloids and Surfaces A, vol. 368, no. 1–3, pp. 58–63, 2010.
[54]  H. Bar, D. K. Bhui, G. P. Sahoo, P. Sarkar, S. P. De, and A. Misra, “Green synthesis of silver nanoparticles using latex of Jatropha curcas,” Colloids and Surfaces A, vol. 339, no. 1–3, pp. 134–139, 2009.
[55]  V. Baskaralingam, C. G. Sargunar, Y. C. Lin, and J. C. Chen, “Green synthesis of silver nanoparticles through Calotropis gigantea leaf extracts and evaluation of antibacterial activity against Vibrio alginolyticus,” Nanotechnology Development, vol. 2, no. 1, article e3, 2012.
[56]  L. Castro, M. L. Blázquez, J. A. Mu?oz, F. González, C. García-Balboa, and A. Ballester, “Biosynthesis of gold nanowires using sugar beet pulp,” Process Biochemistry, vol. 46, no. 5, pp. 1076–1082, 2011.
[57]  S. P. Chandran, M. Chaudhary, R. Pasricha, A. Ahmad, and M. Sastry, “Synthesis of gold nanotriangles and silver nanoparticles using Aloe vera plant extract,” Biotechnology Progress, vol. 22, no. 2, pp. 577–583, 2006.
[58]  S. P. Dubey, M. Lahtinen, and M. Sillanp??, “Green synthesis and characterizations of silver and gold nanoparticles using leaf extract of Rosa rugosa,” Colloids and Surfaces A, vol. 364, no. 1–3, pp. 34–41, 2010.
[59]  A. Kaler, R. Nankar, M. S. Bhattacharyya, and U. C. Banerjee, “Extracellular biosynthesis of silver nanoparticles using aqueous extract of Candida viswanathii,” Journal of Bionanoscience, vol. 5, no. 1, pp. 53–58, 2011.
[60]  J. Kesharwani, K. Y. Yoon, J. Hwang, and M. Rai, “Phytofabrication of silver nanoparticles by leaf extract of Datura metel: hypothetical mechanism involved in synthesis,” Journal of Bionanoscience, vol. 3, no. 1, pp. 39–44, 2009.
[61]  A. T. Marshall, R. G. Haverkamp, C. E. Davies, J. G. Parsons, J. L. Gardea-Torresdey, and D. van Agterveld, “Accumulation of gold nanoparticles in Brassic juncea,” International Journal of Phytoremediation, vol. 9, no. 3, pp. 197–206, 2007.
[62]  A. Singh, D. Jain, M. K. Upadhyay, N. Khandelwal, and H. N. Verma, “Green synthesis of silver nanoparticles using Argemone mexicana leaf extract and evaluation of their antimicrobial activities,” Digest Journal of Nanomaterials and Biostructures, vol. 5, no. 2, pp. 483–489, 2010.
[63]  J. Y. Song, H. K. Jang, and B. S. Kim, “Biological synthesis of gold nanoparticles using Magnolia kobus and Diopyros kaki leaf extracts,” Process Biochemistry, vol. 44, no. 10, pp. 1133–1138, 2009.
[64]  V. Kumar and S. K. Yadav, “Plant-mediated synthesis of silver and gold nanoparticles and their applications,” Journal of Chemical Technology and Biotechnology, vol. 84, no. 2, pp. 151–157, 2009.
[65]  K. Mukunthan and S. Balaji, “Cashew apple juice (Anacardium occidentale L.) speeds up the synthesis of silver nanoparticles,” International Journal of Green Nanotechnology, vol. 4, no. 2, pp. 71–79, 2012.
[66]  X. Li, H. Xu, Z. S. Chen, and G. Chen, “Biosynthesis of nanoparticles by microorganisms and their applications,” Journal of Nanomaterials, vol. 2011, Article ID 270974, 16 pages, 2011.
[67]  M. Safaepour, A. R. Shahverdi, H. R. Shahverdi, M. R. Khorramizadeh, and G. A. Reza, “Green synthesis of small silver nanoparticles using geraniol and its cytotoxicity against Fibrosarcoma-Wehi 164,” Avicenna Journal of Medical Biotechnology, vol. 1, no. 2, pp. 111–115, 2009.
[68]  S. Kaviya, J. Santhanalakshmi, and B. Viswanathan, “Biosynthesis of silver nano-flakes by Crossandra infundibuliformis leaf extract,” Materials Letters, vol. 67, no. 1, pp. 64–66, 2012.
[69]  N. Ahmad, S. Sharma, V. Singh, S. F. Shamsi, A. Fatma, and B. R. Mehta, “Biosynthesis of silver nanoparticles from Desmodium triflorum: a novel approach towards weed utilization,” Biotechnology Research International, vol. 2011, Article ID 454090, 8 pages, 2011.
[70]  C. Krishnaraj, E. G. Jagan, S. Rajasekar, P. Selvakumar, P. T. Kalaichelvan, and N. Mohan, “Synthesis of silver nanoparticles using Acalypha indica leaf extracts and its antibacterial activity against water borne pathogens,” Colloids and Surfaces B, vol. 76, no. 1, pp. 50–56, 2010.
[71]  J. S. Taurozzi, V. A. Hackley, and M. R. Wiesner, “CEINT/NIST protocol for preparation of nanoparticle dispersions from powdered material using ultrasonic disruption,” National Institute of Standards and Technology, Materials Science and Engineering Laboratory, Gaithersburg, Md, USA.
[72]  G. Pang, X. Xu, V. Markovich et al., “Preparation of La1-xSrxMnO3 nanoparticles by sonication-assisted coprecipitation,” Materials Research Bulletin, vol. 38, no. 1, pp. 11–16, 2003.
[73]  Z. Lei, L. Zhang, and X. Wei, “One-step synthesis of silver nanoparticles by sonication or heating using amphiphilic block copolymer as templates,” Journal of Colloid and Interface Science, vol. 324, no. 1-2, pp. 216–219, 2008.
[74]  R. O. Al-Kaysi, A. M. Müller, T. S. Ahn, S. Lee, and C. J. Bardeen, “Effects of sonication on the size and crystallinity of stable zwitterionic organic nanoparticles formed by reprecipitation in water,” Langmuir, vol. 21, no. 17, pp. 7990–7994, 2005.
[75]  A. M. Shanmugharaj and S. H. Ryu, “Excellent electrochemical performance of graphene-silver nanoparticle hybrids prepared using a microwave spark assistance process,” Electrochimica Acta, vol. 74, pp. 207–214, 2012.
[76]  K. S. Hui, K. N. Hui, D. A. Dinh et al., “Green synthesis of dimension-controlled silver nanoparticle-graphene oxide with in situ ultrasonication,” Acta Materialia, vol. 64, pp. 326–332, 2014.
[77]  S. Taherian, M. H. Entezari, and N. Ghows, “Sono-catalytic degradation and fast mineralization of p-chlorophenol: La0.7Sr0.3MnO3 as a nano-magnetic green catalyst,” Ultrasonics Sonochemistry, vol. 20, no. 6, pp. 1419–1427, 2013.
[78]  S. K. Saha, P. Chowdhury, P. Saini, and S. P. S. Babu, “Ultrasound assisted green synthesis of poly(vinyl alcohol) cappedsilver nanoparticles for the study of its antifilarial efficacy,” Applied Surface Science, vol. 288, pp. 625–632, 2014.
[79]  S. Anandhakumar and A. M. Raichur, “Polyelectrolyte/silver nanocomposite multilayer films as multifunctional thin film platforms for remote activated protein and drug delivery,” Acta Biomaterialia, vol. 9, no. 11, pp. 8864–8874, 2013.
[80]  K. Vimala, S. Sundarraj, M. Paulpandi, S. Vengatesan, and S. Kannan, “Green synthesized doxorubicin loaded zinc oxide nanoparticles regulates the Bax and Bcl-2 expression in breast and colon carcinoma,” Process Biochemistry, vol. 49, no. 1, pp. 160–172, 2014.
[81]  N. Ghows and M. H. Entezari, “Sono-synthesis of core-shell nanocrystal (CdS/TiO2) without surfactant,” Ultrasonics Sonochemistry, vol. 19, no. 5, pp. 1070–1078, 2012.
[82]  R. Konwarh, N. Karak, C. E. Sawian, S. Baruah, and M. Mandal, “Effect of sonication and aging on the templating attribute of starch for “green” silver nanoparticles and their interactions at bio-interface,” Carbohydrate Polymers, vol. 83, no. 3, pp. 1245–1252, 2011.

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