全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Hydrodynamics of a Novel Design Circulating Fluidized Bed Steam Reformer Operating in the Dense Suspension Upflow Regime

DOI: 10.1155/2014/935750

Full-Text   Cite this paper   Add to My Lib

Abstract:

Circulating fluidized bed steam reformers (CFBSR) represent an important alternative for hydrogen production, a promising energy carrier. Although the reactor hydrodynamics play crucial role, modeling efforts to date are limited to one-dimensional models, thus ignoring many of the flow characteristics of fluidized beds that have strong effects on the reactor efficiency. The flow inside the riser is inherently complex and requires at least two-dimensional modeling to capture its details. In the present work, the computational fluid dynamics (CFD) simulations of the hydrodynamics of the riser part of a novel CFBSR were carried out using two-phase Eulerian-Eulerian approach coupled with kinetic theory of granular flow and K-ε model. Cold flow simulations were carried under different fluidization regimes. It was found that catalyst of Geldart's type “A” particle is more efficient for flow inside the catalytic reactor and dense suspension upflow (DSU) fluidization regime yields the best homogeneous catalyst distribution in the riser and thus best reactor performance. The optimum range for catalyst flux was found to be higher than 1150?kg/m2·s for a gas flux of 6.78?kg/m2·s. It was also noted that the value of 500?Kg/m2·s for catalyst flux represents the critical value below which the riser will operate under pneumatic transport regime. 1. Introduction Hydrogen has many uses in chemical and energy industries; it is an essential raw material and component for ammonia production and in all hydrocracking plants. It is gaining much attention as the second important energy carrier after electricity [1]. The continuous and fast development in fuel cells technology increased the importance of hydrogen as it is the most efficient feed for fuel cells since it produces only water when utilized [2]. Steam reforming of hydrocarbons is the main production method of hydrogen, especially from methane [3], although the use of higher hydrocarbons [4] and biodiesel [5, 6] is gaining more attention. Typically, the process involves a fixed bed reactor with special focus on heat transfer efficiency of the system. New reformer designs are investigated to attempt to overcome the process mass transfer, equilibrium limitations, and catalyst deactivation hurdle. A comparison between different reformers generations is presented in Table 1. The fundamental structure of the circulating fluidized bed membrane reactor (CFBMR), the most recent design, is shown schematically in Figure 1. Table 1: Comparison between fixed bed steam reformers, bubbling fluidized bed steam reformers (BFBMSR),

References

[1]  V. A. Goltsov and T. N. Veziroglu, “A step on the road to hydrogen civilization,” International Journal of Hydrogen Energy, vol. 27, no. 7-8, pp. 719–723, 2002.
[2]  L. F. Brown, “A comparative study of fuels for on-board hydrogen production for fuel-cell-powered automobiles,” International Journal of Hydrogen Energy, vol. 26, no. 4, pp. 381–397, 2001.
[3]  M. V. Twigg, Catalyst Handbook, Wolfe, London, UK, 2nd edition, 1989.
[4]  T. S. Christensen, “Adiabatic prereforming of hydrocarbons-an important step in syngas production,” Applied Catalysis A, vol. 138, no. 2, pp. 285–309, 1996.
[5]  D. Wang, S. Czernik, D. Montané, M. Mann, and E. Chornet, “Biomass to hydrogen via fast pyrolysis and catalytic steam reforming of the pyrolysis oil or its fractions,” Industrial and Engineering Chemistry Research, vol. 36, no. 5, pp. 1507–1518, 1997.
[6]  S. Czernik, R. French, C. Feik, E. Chornet, C. Gregoire-Padró, and F. Lau, “Production of hydrogen from biomass by pyrolysis/ steam reforming,” Advances in Hydrogen Energy, pp. 87–91, 2000.
[7]  J. R. Grace, A. S. Issangya, D. Bai, H. Bi, and J. Zhu, “Situating the high-density circulating fluidized bed,” AIChE Journal, vol. 45, no. 10, pp. 2108–2116, 1999.
[8]  Z. Chen, Y. Yan, and S. S. E. H. Elnashaie, “Novel circulating fast fluidized-bed membrane reformer for efficient production of hydrogen from steam reforming of methane,” Chemical Engineering Science, vol. 58, no. 19, pp. 4335–4349, 2003.
[9]  A. M. AlMuttahar, CFD modeling of the hydrodynamics of circulating fluidised bed riser [Ph.D. thesis], University of Britich Columbia, Vancouver, Canada, 2006.
[10]  J. R. Grace, “Contacting modes and behavior classification of gas-solid and other two-phase suspensions,” Canadian Journal of Chemical Engineering, vol. 64, no. 3, pp. 353–363, 1986.
[11]  S. W. Kim, G. Kirbas, H. Bi, C. J. Lim, and J. R. Grace, “Flow behavior and regime transition in a high-density circulating fluidized bed riser,” Chemical Engineering Science, vol. 59, no. 18, pp. 3955–3963, 2004.
[12]  R. Kumar and K. M. Pandey, “CFD analysis of circulating fluidized bed combustion,” Engineering Science and Technology, vol. 2, no. 1, pp. 163–174, 2012.
[13]  A. Almuttahar and F. Taghipour, “Computational fluid dynamics of high density circulating fluidized bed riser: study of modeling parameters,” Powder Technology, vol. 185, no. 1, pp. 11–23, 2008.
[14]  J. Bellan and D. Lathouwers, “Modeling of dense gas-solid reactive mixtures applied to biomass pyrolysis in a fluidized bed,” International Journal of Multiphase Flow, vol. 27, no. 12, pp. 2155–2187, 2001.
[15]  B. Wang, T. Li, Q. Sun, W. Ying, and D. Fang, “Solid concentration in circulating fluidized bed reactor for the MTO process,” International Journal of Chemical and Biological Engineering, vol. 3, no. 2, p. 90, 2010.
[16]  T. Boyd, C. Lim, J. Grace, and A. Adris, “Cold modelling of an internally circulating fluidized bed membrane reactor,” in Proceedings of the 12th International Conference on Fluidization- New Horizons in Fluidization Engineering, 2007.
[17]  M. Lim, S. Pang, and J. Nijdam, “Investigation of solids circulation in a cold model of a circulating fluidized bed,” Powder Technology, vol. 226, pp. 57–67, 2012.
[18]  G. Iaquaniello, A. Borruto, E. Lollobattista, G. Narducci, and D. Katsir, “Hydrogen palladium selective membranes: an economic prespective,” in Membrane Reactors for Hydrogen Production Processes, chapter 3, Springer, New York, NY, USA, 2011.
[19]  Z. Li, “Robust low-cost water-gas-shift membrane reactor for high-purity hydrogen production from coal-derived syngas,” DOE Hydrogen Program, 2005.
[20]  S. Deshmukh, S. Heinrich, L. M?rl, M. van Sint Annaland, and J. A. M. Kuipers, “Membrane assisted fluidized bed reactors: potentials and hurdles,” Chemical Engineering Science, vol. 62, no. 1-2, pp. 416–436, 2007.
[21]  M. M. Mousa, S. K. Fateen, and E. A. Ibrahim, “Hydrodynamic characteristics of a novel circulating fluidized bed steam reformer operating in the fast fluidization regime,” International Journal of Chemical Reactor Engineering, vol. 9, p. A104, 2011.
[22]  Z. Chen, Y. Yan, and S. Elnashaie, “Modeling and optimization of a novel membrane reformer for higher hydrocarbons,” AIChE Journal, vol. 49, no. 5, pp. 1250–1265, 2003.
[23]  K. S. Lim, J. X. Zhu, and J. R. Grace, “Hydrodynamics of gas-solid fluidization,” International Journal of Multiphase Flow, vol. 21, pp. 141–193, 1995.
[24]  T. Van den Moortel, E. Azario, R. Santini, and L. Tadrist, “Experimental analysis of the gas-particle flow in a circulating fluidized bed using a phase Doppler particle analyzer,” Chemical Engineering Science, vol. 53, no. 10, pp. 1883–1899, 1998.
[25]  M. Van de Velden, J. Baeyens, and K. Smolders, “Solids mixing in the riser of a circulating fluidized bed,” Chemical Engineering Science, vol. 62, no. 8, pp. 2139–2153, 2007.
[26]  H. Zhu and J. Zhu, “Characterization of fluidization behavior in the bottom region of CFB risers,” Chemical Engineering Journal, vol. 141, no. 1–3, pp. 169–179, 2008.
[27]  D. Geldart, “Types of gas fluidization,” Powder Technology, vol. 7, no. 5, pp. 285–292, 1973.
[28]  Z. Chen, Y. Yan, and S. Elnashaie, “Hydrogen production and carbon formation during the steam reformer of heptane in a novel circulating fluidized bed membrane reformer,” Industrial and Engineering Chemistry Research, vol. 43, no. 6, pp. 1323–1333, 2004.
[29]  D. Gidaspow, R. Bezburuah, and J. Ding, “Hydrodynamics of circulating fluidized beds, kinetic theory approach,” in Proceedings of the 7th Engineering Foundation Conference on Fluidization, Fluidization VII, 1992.
[30]  C. Y. Wen and Y. H. Yu, “Mechanics of fluidization,” Chemical Engineering Progress Symposium Series, vol. 62, 1966.
[31]  M. Syamlal and T. J. O. 'Brien, “Computer simulation of bubbles in a fluidized bed,” AIChE Symposium Series, 1989.
[32]  H. Arastoopour, P. Pakdel, and M. Adewumi, “Hydrodynamic analysis of dilute gas-solids flow in a vertical pipe,” Powder Technology, vol. 62, no. 2, pp. 163–170, 1990.
[33]  C. Lun and S. B. Savage, “The effects of an impact velocity dependent coefficient of restitution on stresses developed by sheared granular materials,” Acta Mechanica, vol. 63, no. 1–4, pp. 15–44, 1986.
[34]  S. Ogawa, A. Umemura, and N. Oshima, “On the equations of fully fluidized granular materials,” Zeitschrift für angewandte Mathematik und Physik ZAMP, vol. 31, no. 4, pp. 483–493, 1980.
[35]  J. L. Sinclair and R. Jackson, “Gas-particle flow in a vertical pipe with particle-particle interactions,” AIChE Journal, vol. 35, no. 9, pp. 1473–1486, 1989.
[36]  C. M. Hrenya and J. L. Sinclair, “Effects of particle-phase turbulence in gas-solid flows,” AIChE Journal, vol. 43, no. 4, pp. 853–869, 1997.
[37]  J. J. Nieuwland, M. Van Sint Annaland, J. A. M. Kuipers, and W. P. M. Van Swaaij, “Hydrodynamic modeling of gas/particle flows in riser reactors,” AIChE Journal, vol. 42, no. 6, pp. 1569–1582, 1996.
[38]  A. Almuttahar and F. Taghipour, “Computational fluid dynamics of high density circulating fluidized bed riser: study of modeling parameters,” Powder Technology, vol. 185, no. 1, pp. 11–23, 2008.
[39]  E. J. Bolio, J. A. Yasuna, and J. L. Sinclair, “Dilute turbulent gas-solid flow in risers with particle-particle interactions,” AIChE Journal, vol. 41, no. 6, pp. 1375–1388, 1995.
[40]  D. J. Patil, M. van Sint Annaland, and J. Kuipers, “Modeling of turbulent gas-particle flows in risers: influence of turbulence modulation on the radial solids segregation,” in Proceedings of the 8th International Conference on Circulating Fluidized Beds, Hangzhou, China, 2005.
[41]  S. Benyahia, H. Arastoopour, T. M. Knowlton, and H. Massah, “Simulation of particles and gas flow behavior in the riser section of a circulating fluidized bed using the kinetic theory approach for the particulate phase,” Powder Technology, vol. 112, no. 1-2, pp. 24–33, 2000.
[42]  L. Huilin and D. Gidaspow, “Hydrodynamics of binary fluidization in a riser: CFD simulation using two granular temperatures,” Chemical Engineering Science, vol. 58, no. 16, pp. 3777–3792, 2003.
[43]  V. Jiradilok, D. Gidaspow, S. Damronglerd, W. J. Koves, and R. Mostofi, “Kinetic theory based CFD simulation of turbulent fluidization of FCC particles in a riser,” Chemical Engineering Science, vol. 61, no. 17, pp. 5544–5559, 2006.
[44]  H. Zhou, G. Flamant, and D. Gauthier, “Modeling of the turbulent gas-particle flow structure in a two-dimensional circulating fluidized bed riser,” Chemical Engineering Science, vol. 62, no. 1-2, pp. 269–280, 2007.
[45]  J. A. Pita and S. Sundaresan, “Developing flow of a gas-particle,” AIChE Journal, vol. 39, no. 4, pp. 541–552, 1993.
[46]  M. Tartan, D. Gidaspow, R. Mostofi, and Y. Shin, Computational and Experimental Modeling of Slurry Bubble Column Reactors: Measurement and Computation of Turbulence in Risers, US Department of Energy, Washington, DC, USA, 2001.
[47]  V. Ranade, Computational Flow Modeling for Chemical Reactor Engineering, Process Systems Engineering, Academic Press, London, UK, 2002.
[48]  P. C. Johnson and R. Jackson, “Frictional-collisional constitutive relations for granular materials, with application to plane shearing,” Journal of Fluid Mechanics, vol. 176, pp. 67–93, 1987.
[49]  V. Ranade, “Modeling of gas-solid flows in FCC riser: fully developed flow,” in Proceedings of the 2nd International Conference on CFD in Minerals and Process Industries Melbourne, Melbourne, Australia, 1999.
[50]  T. Li, J. Grace, and X. Bi, “Study of wall boundary condition in numerical simulations of bubbling fluidized beds,” Powder Technology, vol. 203, no. 3, pp. 447–457, 2010.
[51]  A. Neri and D. Gidaspow, “Riser hydrodynamics: simulation using kinetic theory,” AIChE Journal, vol. 46, no. 1, pp. 52–67, 2000.
[52]  M. Kruse and J. Werther, “2D gas and solids flow prediction in circulating fluidized beds based on suction probe and pressure profile measurements,” Chemical Engineering and Processing, vol. 34, no. 3, pp. 185–203, 1995.
[53]  C. H. Ibsen, T. Solberg, B. H. Hjertager, and F. Johnsson, “Laser Doppler anemometry measurements in a circulating fluidized bed of metal particles,” Experimental Thermal and Fluid Science, vol. 26, no. 6-7, pp. 851–859, 2002.
[54]  A. Issangya, J. Grace, D. Bai, and J. Zhu, “Further measurements of flow dynamics in a high-density circulating fluidized bed riser,” Powder Technology, vol. 111, no. 1-2, pp. 104–113, 2000.
[55]  A. Passalcqua, CFD simulation of gas-solid flows [Ph.D. thesis], Politecnico di Torino, Torino, Italy, 2006.
[56]  S. Benyahia, H. Arastoopour, and T. M. Knowlton, “Two-dimensional transient numerical simulation of solids and gas flow in the riser section of a circulating fluidized bed,” Chemical Engineering Communications, vol. 189, no. 2, pp. 510–527, 2002.
[57]  J. Ding and D. Gidaspow, “A bubbling fluidization model using kinetic theory of granular flow,” AIChE Journal, vol. 36, no. 4, pp. 523–538, 1990.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133