Role of molecular diffusion in the recovery of water flood residual oil

Traditionally, carbon dioxide (CO2) injection has been considered an inefficient method for enhancing oil recovery from naturally fractured reservoirs. Obviously, it would be useful to experimentally investigate the efficiency of waterflooding naturally fractured reservoirs followed by carbon dioxide (CO2) injection. This issue was investigated by performing water imbibition followed by CO2 gravity drainage experiments on artificially fractured cores at reservoir conditions. The experiments were designed to illustrate the actual process of waterflooding and CO2 gravity drainage in a naturally fractured reservoir in the Brass Area, Bayelsa. The results demonstrate that CO2 gravity drainage could significantly increase oil recovery after a waterflood. During the experiments, the effects of different parameters such as permeability, initial water saturation and injection scheme was also examined. It was found that the efficiency of the CO2 gravity drainage decrease as the rock permeability decreases and the initial water saturation increases. Cyclic CO2 injection helped to improve oil recovery during the CO2 gravity drainage process which alters the water imbibition. Oil samples produced in the experiment were analyzed using gas chromatography to determine the mechanism of CO2-improved oil production from tight matrix blocks. The results show that lighter components are extracted and produced early in the test. The results of these experiments validate the premises that CO2 could be used to recover oil from a tight and unconfined matrix efficiently.