|
|
超临界水氧化技术处理难降解有机废液研究
|
Abstract:
超临界水氧化技术具有净化效率高、反应速率快、有机物降解彻底、无二次污染等优点，常用于高浓度难降解有机废液无害化处理中。本文比较了超临界水氧化法、焚烧法、Fenton试剂法、湿式空气氧化法处理有机废液的特点及其处理不同浓度、不同热值有机废液的应用条件，介绍了超临界水氧化降解火炸药废液、推进剂废液、放射性废液等的反应机理、工艺运行参数及其主要元素降解路径，为超临界水氧化处理难降解有机废液大规模工程应用奠定了基础。
Supercritical water oxidation (SCWO) technology has the advantages of high efficiency, fast reaction rate, complete degradation of organic and no secondary pollution. It is often used in the harmless treatment of high-concentration refractory organic waste liquid. This paper compares the characteristics of SCWO, incineration method, Fenton reagent method and wet air oxidation in the treatment of organic waste liquid and its application conditions for the different concentrations and calorific values of organic waste liquid. The reaction mechanism, process operation parameters and degradation paths of the main elements of SCWO treatment explosive waste liquid, propellant waste liquid, and radioactive waste liquid are introduced, which lays a foundation for SCWO large-scale engineering application.
| [1] | Medoll, M. (1982) Treatment for Oxidation of Organic Material in Supercritical Water. US: 4338199, 1982-07-06. |
| [2] | Buelow, S.J., Allen, D., Anderson, G.K., et al. (2002) Destruction of Energetic Materials in Super-critical Water. US: AFRL-ML-TY-TR-2002-4522. |
| [3] | Brunner, G. (2009) Near Critical and Supercritical Water. Part I. Hydrolytic and Hydrothermal Processes. Journal of Supercritical Fluids, 47, 373-381. https://doi.org/10.1016/j.supflu.2008.09.002 |
| [4] | Brunner, G. (2009) Near Critical and Supercritical Water. Part II: Oxidative Processes. Journal of Supercritical Fluids, 47, 382-390. https://doi.org/10.1016/j.supflu.2008.09.001 |
| [5] | Zhang, F.M., Shen, B.Y., Su, C.J., Xu, C.Y., et al. (2017) Ener-gy Consumption and Exergy Analyses of a Supercritical Water Oxidation System with a Transpiring Wall Reactor. En-ergy Conversion and Management, 145, 82-92.
https://doi.org/10.1016/j.enconman.2017.04.082 |
| [6] | Marrone, P.A. (2013s) Supercritical Water Oxidation-Current Status of Full-Scale Commercial Activity for Waste Destruction. The Journal of Supercritical Fluids, 79, 283-288. https://doi.org/10.1016/j.supflu.2012.12.020 |
| [7] | 马承愚, 彭英利. 高浓度难降解有机废水的治理与控制[M]. 第2版. 北京: 化学工业出版社, 2011. |
| [8] | 张家荣, 赵廷元. 工程常用物质的热物理性质手册[M]. 北京: 新时代出版社, 1989: 127-128. |
| [9] | 张亚朋, 侯吉礼, 崔龙鹏, 等. 催化超临界水氧化技术研究进展[J]. 工业水处理, 2022, 42(1): 29-37. |
| [10] | 石德智, 张金露, 胡春艳, 等. 超临界水氧化技术处理污泥的研究与应用进展[J]. 化工学报, 2017, 68(1): 37-49. |
| [11] | 常双君, 刘玉存. 超临界水氧化处理TNT-RDX混合炸药废水的试验[J]. 环境工程, 2009, 27(3): 36-38+48. |
| [12] | 常双君, 刘玉存, 董国庆, 等. TNT在超临界水中的氧化反应动力学[J]. 火炸药学报, 2010, 33(1): 56-61. |
| [13] | 赵保国, 刘玉存, 耿鹏印. 超临界水氧化降解DNT废水的实验研究[J]. 化学工程, 2008, 36(10): 62-65. |
| [14] | 孟兆龙, 刘玉存, 柴涛. 超临界水氧化处理DDNP废水的动力学研究[J]. 火炸药学报, 2007, 30(5): 78-80. |
| [15] | 赵保国, 刘玉存, 耿鹏印, 等. 超临界水氧化HMX废水的动力学研究[J]. 火炸药学报, 2008, 31(3): 61-63+70. |
| [16] | 赵军霞, 柴涛, 赵双喜, 等. 超临界水氧化六硝基菧废水及其对反应釜腐蚀研究[J]. 水处理技术, 2010, 35(12): 50-54. |
| [17] | 侯瑞琴, 刘占卿, 马文, 等. 高浓度偏二甲肼废液近临界水氧化处理试验研究[J]. 给水排水, 2019, 45(4): 82-87. |
| [18] | 兰树仁, 柴涛, 刘玉存, 等. 催化超临界水氧化技术处理硝酸肼和无水肼[J]. 工业水处理, 2020, 40(9): 80-84. |
| [19] | 柴涛, 刘玉存, 高亚华, 等. 间歇式超临界水氧化处理核电站废弃阳离子交换树脂研究[J]. 核科学与工程, 2019, 39(4): 646-651. |
| [20] | 赵光明, 刘玉存, 柴涛, 等. 有机废水过热近临界水氧化技术研究[J]. 科技导报, 2015, 33(3): 1-5. |
| [21] | 张家明. 超临界水氧化过程动力学及氮元素转移机理研究[D]: [博士学位论文]. 济南: 山东大学, 2012. |
| [22] | 高亚华. 超临界水氧化处理阴阳离子交换树脂的研究[D]: [硕士学位论文]. 太原: 中北大学, 2018. |
| [23] | Kim, K., Kim, K.S., Choi, M., Son, S.H. and Han, J.H. (2012) Treat-ment of Ion Exchange Resins Used in Nuclear Power Plants by Super- and Sub-Critical Water Oxidation—A Road to Commercial Plant from Bench-Scale Facility. Chemical Engineering Journal, 189-190, 213-221. https://doi.org/10.1016/j.cej.2012.02.060 |
| [24] | 赵光明, 刘玉存, 柴涛, 等. 连续型超临界水氧化系统出水酸碱性分流试验研究[J]. 安全与环境学报, 2016, 16(4): 297-301. |
